Non-radiative relaxation of UV photoexcited phenylalanine residues: Probing the role of conical intersections by chemical substitution
M Mališ, Y Loquais, E Gloaguen, C Jouvet… - Physical Chemistry …, 2014 - pubs.rsc.org
Physical Chemistry Chemical Physics, 2014•pubs.rsc.org
A conformation-selective photophysics study in phenylalanine model peptides, combining
pump–probe gas phase experiments and excited state calculations, highlights for the first
time the quenching properties of a primary amide group (through its nπ* excited state) along
with the effect of vibrational energy that facilitates access to the conical intersection area.
pump–probe gas phase experiments and excited state calculations, highlights for the first
time the quenching properties of a primary amide group (through its nπ* excited state) along
with the effect of vibrational energy that facilitates access to the conical intersection area.
A conformation-selective photophysics study in phenylalanine model peptides, combining pump–probe gas phase experiments and excited state calculations, highlights for the first time the quenching properties of a primary amide group (through its nπ* excited state) along with the effect of vibrational energy that facilitates access to the conical intersection area.
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