Novel dinuclear and trinuclear palladium β-diiminate complexes containing amido–chloro double-bridges
A Hadzovic, J Janetzko, D Song - Dalton Transactions, 2008 - pubs.rsc.org
A Hadzovic, J Janetzko, D Song
Dalton Transactions, 2008•pubs.rsc.orgWe report the formation of an unexpected trinuclear palladium β-diiminate complex from the
decomposition of [Pd (Ph2nacnac)(Cl)(4-H2NC6H4-tBu)](nacnac= β-diiminate derived from
acetylacetone), the proposed reaction pathway, and the synthesis of the first dinuclear
palladium complex with an amido–chloro double-bridge.
decomposition of [Pd (Ph2nacnac)(Cl)(4-H2NC6H4-tBu)](nacnac= β-diiminate derived from
acetylacetone), the proposed reaction pathway, and the synthesis of the first dinuclear
palladium complex with an amido–chloro double-bridge.
We report the formation of an unexpected trinuclear palladium β-diiminate complex from the decomposition of [Pd(Ph2nacnac)(Cl)(4-H2NC6H4-tBu)] (nacnac = β-diiminate derived from acetylacetone), the proposed reaction pathway, and the synthesis of the first dinuclear palladium complex with an amido–chloro double-bridge.
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