Nucleation at high pressure. I. Theoretical considerations

CCM Luijten, MEH Van Dongen - The Journal of chemical physics, 1999 - pubs.aip.org
A theoretical approach is presented that accounts for the influence of high pressure
background gases on the vapor-to-liquid nucleation process. The key idea is to treat the
carrier gas pressure as a perturbation parameter that modifies the properties of the
nucleating substance. Two important mechanisms are identified in this respect: With
increasing carrier gas pressure, the saturated vapor density tends to increase enhancement
effect, whereas the surface tension generally decreases. Several routes to obtain data for …
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