… Herein, we describe the on-surface synthesis of molecular … To date, on-surface dehalogenative
aryl–aryl coupling has … to obtain four- and six-membered carbon rings at predetermined …

… cyclization has been further realized based on more complicated ortho-dihalo substitutions
(Figure S1), resulting in the generation of four- and six-membered ring scaffolds… of on-surface …

… On-surface reactions of DBPZ have not been detected on the Au(111) until a higher …
arms, each containing three six-membered rings. The middle ring exhibits the most negative …

… a rich on-surface chemistry. In particular, arynes have been generated and studied on-surface,
showing that the reactivity is preserved even at cryogenic temperatures. On-surface aryne …

… On-surface synthesis under ultrahigh vacuum conditions is a … formation of an extra six-membered
ring. Despite its extensive … to use DDA reactions as a novel on-surface synthesis tool. …

… On-surface synthesis (OSS) has shown its great potential in … activity toward a specific on-surface
reaction, thus impacting … differentiates the heterogeneous on-surface synthesis from the …

… On-Surface Synthesis On-surface synthesis commonly proceeds by depositing a reactant
precursor onto clean metallic substrates held at room temperature (RT), followed by annealing …

… On-surface synthesis provides a versatile and convenient … ., the cycloaddition reactions of
ortho-dihalotetracenes on an Ag(… on-surface synthesis and characterization of LPs (Figure 1a). …

… S), built of the bimolecular sandwichlike units, are no longer present in the racemic
overlayer and, instead, they are decomposed and replaced by the structurally different six-membered …

… In on-surface synthesis, thermal activation is applied for promoting covalent bond … as
four and two bright protrusions located symmetrically around the octagon and tetragon rings, …