Optical properties of core/multishell CdSe/Zn (S, Se) nanocrystals

J Bleuse, S Carayon, P Reiss - Physica E: Low-dimensional Systems and …, 2004 - Elsevier
CdSe nanocrystals are now known as highly efficient fluorescent light sources. Their
efficiency is however strongly dependent on the quality of the passivation layers. We show
here that using a ZnSe/ZnS bi-layer shell leads to a larger photoluminescence yield than
both ZnSe and ZnS simple shells. The intermediate ZnSe layer acts as a lattice parameter
adaptation layer to improve on the core/shell interface quality, while the ZnS outer shell
maximizes the exciton confinement.
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