Optical spectroscopy of complex open--shell ions

F Torretti, A Windberger, A Ryabtsev, S Dobrodey… - Physical Review A, 2017 - APS
F Torretti, A Windberger, A Ryabtsev, S Dobrodey, H Bekker, W Ubachs, R Hoekstra
Physical Review A, 2017APS
We analyze the complex level structure of ions with many-valence-electron open-[Kr] 4 dm
subshells (m= 7–4) with ab initio calculations based on configuration-interaction many-body
perturbation theory (CI+ MBPT). Charge-state-resolved optical and extreme ultraviolet (EUV)
spectra of Sn 7+–Sn 10+ ions were obtained using an electron beam ion trap. Semiempirical
spectral fits carried out with the orthogonal parameters technique and cowan code
calculations lead to 90 identifications of magnetic-dipole transitions and the determination of …
We analyze the complex level structure of ions with many-valence-electron open-[Kr]  subshells () with ab initio calculations based on configuration-interaction many-body perturbation theory (CI+MBPT). Charge-state-resolved optical and extreme ultraviolet (EUV) spectra of ions were obtained using an electron beam ion trap. Semiempirical spectral fits carried out with the orthogonal parameters technique and cowan code calculations lead to 90 identifications of magnetic-dipole transitions and the determination of 79 energy ground-configuration levels, questioning some earlier EUV-line assignments. Our results confirm the ab initio predictive power of CI+MBPT calculations for these complex electronic systems.
American Physical Society
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