heteroaromatic nucleophiles. By using an organocatalytic photoredox system, a direct
method to construct a diverse of (Z)‐α‐azole enamides from ynamides and pyrazoles, as
well as triazoles, benzotriazoles, indazoles, and tetrazoles, is developed, thus providing a
photocatalytically synthetic route to heterocyclic motifs common in medicinal agents. Based
on the mechanistic studies, the hydroamination is postulated to operate via a mechanism in …