Path to the measurement of positive gain on the 1315-nm transition of atomic iodine pumped by O/sub 2/(a/sup 1//spl Delta/) produced in an electric discharge

DL Carroll, JT Verdeyen, DM King… - IEEE Journal of …, 2005 - ieeexplore.ieee.org
DL Carroll, JT Verdeyen, DM King, JW Zimmerman, JK Laystrom, BS Woodard…
IEEE Journal of Quantum Electronics, 2005ieeexplore.ieee.org
Laser action at 1315 nm on the I (/sup 2/P/sub 1/2/)/spl rarr/I (/sup 2/P/sub 3/2/) transition of
atomic iodine is conventionally obtained by a near-resonant energy transfer from O/sub
2/(a/sup 1//spl Delta/) which is produced using wet-solution chemistry. The system difficulties
of chemically producing O/sub 2/(a/sup 1//spl Delta/) have motivated investigations into gas
phase methods to produce O/sub 2/(a/sup 1//spl Delta/) using low-pressure electric
discharges. We report on the path that led to the measurement of positive gain on the 1315 …
Laser action at 1315 nm on the I(/sup 2/P/sub 1/2/)/spl rarr/I(/sup 2/P/sub 3/2/) transition of atomic iodine is conventionally obtained by a near-resonant energy transfer from O/sub 2/(a/sup 1//spl Delta/) which is produced using wet-solution chemistry. The system difficulties of chemically producing O/sub 2/(a/sup 1//spl Delta/) have motivated investigations into gas phase methods to produce O/sub 2/(a/sup 1//spl Delta/) using low-pressure electric discharges. We report on the path that led to the measurement of positive gain on the 1315-nm transition of atomic iodine where the O/sub 2/(a/sup 1//spl Delta/) was produced in a flowing electric discharge. Atomic oxygen was found to play both positive and deleterious roles in this system, and as such the excess atomic oxygen was scavenged by NO/sub 2/ to minimize the deleterious effects. The discharge production of O/sub 2/(a/sup 1//spl Delta/) was enhanced by the addition of a small proportion of NO to lower the ionization threshold of the gas mixture. The electric discharge was upstream of a continuously flowing supersonic cavity, which was employed to lower the temperature of the flow and shift the equilibrium of atomic iodine more in favor of the I(/sup 2/P/sub 1/2/) state. A tunable diode laser system capable of scanning the entire line shape of the (3,4) hyperfine transition of iodine provided the gain measurements.
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