Phosphinite-Ni (0) mediated formation of a phosphide-Ni (II)-OCOOMe species via uncommon metal–ligand cooperation
YE Kim, S Oh, S Kim, O Kim, J Kim… - Journal of the …, 2015 - ACS Publications
Reversible transformations are observed between a phosphide-nickel (II) alkoxide and a
phosphinite-nickel (0) species via a P–O bond formation coupled with a 2-e–redox change
at the nickel center. In the forward reaction, the nickel (0) dinitrogen species (PPOMeP) Ni
(N2)(2) and {(PPOMeP) Ni} 2 (μ-N2)(3) were formed from the reaction of (PPP) NiCl (1) with
a methoxy anion. In the backward reaction, a (PPP) Ni (II) moiety was regenerated from the
CO2 reaction of 3 with the concomitant formation of a methyl carbonate ligand in (PPP) Ni …
phosphinite-nickel (0) species via a P–O bond formation coupled with a 2-e–redox change
at the nickel center. In the forward reaction, the nickel (0) dinitrogen species (PPOMeP) Ni
(N2)(2) and {(PPOMeP) Ni} 2 (μ-N2)(3) were formed from the reaction of (PPP) NiCl (1) with
a methoxy anion. In the backward reaction, a (PPP) Ni (II) moiety was regenerated from the
CO2 reaction of 3 with the concomitant formation of a methyl carbonate ligand in (PPP) Ni …
[引用][C] Phosphinite-Ni (0) Mediated Formation of a Phosphide-Ni (II)-OCOOMe Species via Uncommon Metal–Ligand Cooperation
K Yeong-Eun, O Seohee, K Seji, K Onnuri, K Jin… - 2015
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