Phosphites as alternative coreagents for the one-pot aminolysis/thiol-ene synthesis of maleimide-functionalized RAFT polymers
ME Levere, S Pascual… - Journal of Polymer …, 2012 - researchportal.bath.ac.uk
ME Levere, S Pascual, V Montembault, JC Soutif, L Fontaine
Journal of Polymer Science, Part A: Polymer Chemistry, 2012•researchportal.bath.ac.ukThe one-pot aminolysis/thiol-ene chain-end modification between a well-defined
trithiocarbonate-functionalized poly (N-isopropylacrylamide)(DP n= 13 and PDI= 1.06) and
N-phenyl maleimide has been investigated using triethylphosphite (P (OEt) 3) as a
coreagent. A quantitative chain-end functionalization has been obtained as shown by 1 H
NMR spectroscopy and MALDI-TOF mass spectrometry.
trithiocarbonate-functionalized poly (N-isopropylacrylamide)(DP n= 13 and PDI= 1.06) and
N-phenyl maleimide has been investigated using triethylphosphite (P (OEt) 3) as a
coreagent. A quantitative chain-end functionalization has been obtained as shown by 1 H
NMR spectroscopy and MALDI-TOF mass spectrometry.
Abstract
The one-pot aminolysis/thiol-ene chain-end modification between a well-defined trithiocarbonate-functionalized poly (N-isopropylacrylamide)(DP n= 13 and PDI= 1.06) and N-phenyl maleimide has been investigated using triethylphosphite (P (OEt) 3) as a coreagent. A quantitative chain-end functionalization has been obtained as shown by 1 H NMR spectroscopy and MALDI-TOF mass spectrometry.
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