Photochemically assisted fast abiotic oxidation of manganese and formation of δ-MnO 2 nanosheets in nitrate solution
This study introduces a new and previously unconsidered fast abiotic formation of Mn (IV)
oxides. We report photochemically assisted fast abiotic oxidation of Mn2+ (aq) to Mn (IV)(s)
by superoxide radicals generated from nitrate photolysis. This photochemical pathway
generates randomly stacked layered birnessite (δ-MnO2) nanosheets.
oxides. We report photochemically assisted fast abiotic oxidation of Mn2+ (aq) to Mn (IV)(s)
by superoxide radicals generated from nitrate photolysis. This photochemical pathway
generates randomly stacked layered birnessite (δ-MnO2) nanosheets.
This study introduces a new and previously unconsidered fast abiotic formation of Mn(IV) oxides. We report photochemically assisted fast abiotic oxidation of Mn2+ (aq) to Mn(IV) (s) by superoxide radicals generated from nitrate photolysis. This photochemical pathway generates randomly stacked layered birnessite (δ-MnO2) nanosheets.
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