Photodissociation dynamics of H2S at 121.6 nm and a determination of the potential energy function of SH (A 2Σ+)
L Schnieder, W Meier, KH Welge… - The Journal of …, 1990 - pubs.aip.org
A new and improved version of the technique of H atom photofragment translational
spectroscopy has been applied to a study ofH2S photodissociation at 121.6 nm. The primary
fragmentation pathways leading to H+ SH (A) fragments and H+ H+ SeD) atoms are
observed to dominate the product yield; the yield of H atoms formed in conjunction with
ground state SH (X) fragments is undetectably small. The majority of the SH (A) fragments
are formed in their v= 0 level with a rotational state population distribution that spans all …
spectroscopy has been applied to a study ofH2S photodissociation at 121.6 nm. The primary
fragmentation pathways leading to H+ SH (A) fragments and H+ H+ SeD) atoms are
observed to dominate the product yield; the yield of H atoms formed in conjunction with
ground state SH (X) fragments is undetectably small. The majority of the SH (A) fragments
are formed in their v= 0 level with a rotational state population distribution that spans all …
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