Photolysis of Fe (III) carboxylato complexes: Fe (II) quantum yields and reaction mechanisms

C Weller, S Horn, H Herrmann - Journal of Photochemistry and …, 2013 - Elsevier
Fe (III) carboxylato complex photochemistry can be of interest for environmental aqueous
systems, oxidative processing of wastewater or laboratory photochemical applications in
general. A comprehensive dataset of Fe 2+ quantum yields from the photolysis of aqueous
Fe (III) complexes with malonate, succinate, glutarate, dl-tartrate, tartronate, gluconate, dl-
lactate, dl-malate, pyruvate and glyoxalate has been measured. Irradiation techniques
included single laser flash photolysis at 308 and 351 nm and continuous photolysis with a …
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