Generated in high‐Q optical microresonators, dissipative Kerr soliton microcombs constitute broadband optical frequency combs with chip sizes and repetition rates in the microwave to millimeter‐wave range. For frequency metrology applications such as spectroscopy, optical atomic clocks, and frequency synthesizers, octave‐spanning soliton microcombs generated in dispersion‐optimized microresonators are required, which allow self‐referencing for full frequency stabilization. In addition, field‐deployable applications require the generation of such soliton microcombs to be simple, deterministic, and reproducible. Here, a novel scheme to generate self‐emerging solitons in integrated lithium‐niobate microresonators is demonstrated. The single soliton features a broadband spectral bandwidth with dual dispersive waves, allowing 2f–3f self‐referencing. Via harnessing the photorefractive effect of lithium niobate to significantly extend the soliton existence range, a spontaneous yet deterministic single‐soliton formation is observed. The soliton is immune to external perturbation and can operate continuously for over 13 h without active feedback control. Finally, via integration with a pre‐programmed distributed feedback (DFB) laser, turnkey soliton generation is demonstrated. With further improvement of microresonator Q and hybrid integration with chip‐scale laser chips, compact soliton microcomb devices with electronic actuation can be created, which can become central elements for future LiDAR, microwave photonics, and optical telecommunications.