Preventing thermolysis: precursor design for volatile copper compounds
JP Coyle, A Kurek, PJ Pallister, ER Sirianni… - Chemical …, 2012 - pubs.rsc.org
Chemical Communications, 2012•pubs.rsc.org
A copper (I) iminopyrrolidinate was synthesized and evaluated by thermal gravimetric
analysis (TGA), solution based 1H NMR studies and surface chemistry to determine its
thermal stability and decomposition mechanism. Copper (I) tert-butyl-imino-2, 2-
dimethylpyrrolidinate (1) demonstrated superior thermal stability and showed negligible
decomposition in TGA experiments up to 300° C as well as no decomposition in solutions at
165° C over 3 weeks.
analysis (TGA), solution based 1H NMR studies and surface chemistry to determine its
thermal stability and decomposition mechanism. Copper (I) tert-butyl-imino-2, 2-
dimethylpyrrolidinate (1) demonstrated superior thermal stability and showed negligible
decomposition in TGA experiments up to 300° C as well as no decomposition in solutions at
165° C over 3 weeks.
A copper(I) iminopyrrolidinate was synthesized and evaluated by thermal gravimetric analysis (TGA), solution based 1H NMR studies and surface chemistry to determine its thermal stability and decomposition mechanism. Copper(I) tert-butyl-imino-2,2-dimethylpyrrolidinate (1) demonstrated superior thermal stability and showed negligible decomposition in TGA experiments up to 300 °C as well as no decomposition in solutions at 165 °C over 3 weeks.
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