A negative, linear relationship between thermal emissions and a spectral vegetation index has been demonstrated for numerous mid‐latitude ecosystems. In this study, it is hypothesized that the relationship between surface temperature and the normalized difference vegetation index (NDVI) will be linear, but positive in Arctic tundra ecosystems due to the contrast between warm vegetation and the cold soil/moss background. This hypothesis is tested using Advanced Very High Resolution Radiometer (AVHRR) data collected over the North Slope of Alaska on three days during the summer of 1999. Results of the study generally provide support for this hypothesis. However, a consistent relationship observed across two contrasting physiographic provinces on one study day was shown to change the following day and could not be readily explained by differences in satellite zenith angle or observed air temperature. Surface temperatures are shown to respond directly to spatial and temporal variations in air temperature.