Rotational cross sections and rate coefficients of induced by its collision with at low temperature

T Tchakoua, M Pamboundom, BSDR Vamhindi… - Astrophysics and Space …, 2018 - Springer
T Tchakoua, M Pamboundom, BSDR Vamhindi, SGN Engo, O Motapon, M Nsangou
Astrophysics and Space Science, 2018Springer
The potential energy surface (PES) for the CP (X 2 Σ+) CP(X^2\varSigma^+)-He (1 S)
He(^1S) complex has been calculated at the RCCSD (T)-F12/VTZ-F12 level of theory. The
analytic fit of the PES was obtained by using global analytical method. The fitted PES was
used subsequently in the close-coupling approach for the computation of the state-to-state
collisional excitation cross sections of the fine-structure levels of the CP-He complex.
Collision energies were taken up to 1500 cm− 1 and they yield after thermal averaging, state …
Abstract
The potential energy surface (PES) for the - complex has been calculated at the RCCSD(T)-F12/VTZ-F12 level of theory. The analytic fit of the PES was obtained by using global analytical method. The fitted PES was used subsequently in the close-coupling approach for the computation of the state-to-state collisional excitation cross sections of the fine-structure levels of the CP-He complex. Collision energies were taken up to 1500 cm−1 and they yield after thermal averaging, state-to-state rate coefficients up to 200 K. The propensity rules between the lowest fine-structure levels were studied. These rules show, on one hand, a strong propensity in favour of even transitions, and the other hand, that cross sections and collisional rate coefficients for transitions are larger than those for transitions.
Springer
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