He(^1S) complex has been calculated at the RCCSD (T)-F12/VTZ-F12 level of theory. The
analytic fit of the PES was obtained by using global analytical method. The fitted PES was
used subsequently in the close-coupling approach for the computation of the state-to-state
collisional excitation cross sections of the fine-structure levels of the CP-He complex.
Collision energies were taken up to 1500 cm− 1 and they yield after thermal averaging, state …