Second harmonic spectroscopy of ZnO, BiFeO3 and LiNbO3 nanocrystals

J Riporto, M Urbain, Y Mugnier, V Multian… - Optical Materials …, 2019 - opg.optica.org
Optical Materials Express, 2019opg.optica.org
We developed a wavelength-tunable second harmonic scattering experimental setup to
investigate dispersion of the nonlinear optical response of three different nanocrystal
suspensions (LiNbO_3, ZnO and BiFeO_3). Special attention was paid to reproducibility
issues with the implementation of a detailed protocol that allows correcting for the setup
spectral response. The absolute, orientation-averaged second order susceptibilities of the
three nanomaterials were then assessed in the 700-1300? nm spectral range evidencing …
We developed a wavelength-tunable second harmonic scattering experimental setup to investigate dispersion of the nonlinear optical response of three different nanocrystal suspensions (LiNbO_3, ZnO and BiFeO_3). Special attention was paid to reproducibility issues with the implementation of a detailed protocol that allows correcting for the setup spectral response. The absolute, orientation-averaged second order susceptibilities of the three nanomaterials were then assessed in the 700-1300?nm spectral range evidencing very specific optical signatures. The well-defined resonances observed for ZnO and BiFeO_3 near their electronic transitions were found to be poorly described by the Miller’s rule.
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