Steric and electronic effects of ligand substitution on redox-active Fe 4 S 4-based coordination polymers
O Salinas, J Xie, RJ Papoular, NE Horwitz… - Dalton …, 2021 - pubs.rsc.org
One of the notable advantages of molecular materials is the ability to precisely tune
structure, properties, and function via molecular substitutions. While many studies have
demonstrated this principle with classic carboxylate-based coordination polymers, there are
comparatively fewer examples where systematic changes to sulfur-based coordination
polymers have been investigated. Here we present such a study on 1D coordination chains
of redox-active Fe4S4 clusters linked by methylated 1, 4-benzene-dithiolates. A series of …
structure, properties, and function via molecular substitutions. While many studies have
demonstrated this principle with classic carboxylate-based coordination polymers, there are
comparatively fewer examples where systematic changes to sulfur-based coordination
polymers have been investigated. Here we present such a study on 1D coordination chains
of redox-active Fe4S4 clusters linked by methylated 1, 4-benzene-dithiolates. A series of …
Steric and electronic effects of ligand substitution on redox-active Fe4S4-b
O Salinas, J Xie, RJ Papoular, NE Horwitz, E Elkaim… - Dalton T., 2021 - osti.gov
Steric and electronic effects of ligand substitution on redox-active Fe[subscript 4]S[subscript
4]-b (Journal Article) | OSTI.GOV … GOV Journal Article: Steric and electronic effects of
ligand substitution on redox-active Fe[subscript 4]S[subscript 4]-b Steric and electronic
effects of ligand substitution on redox-active Fe[subscript 4]S[subscript 4]-b …
4]-b (Journal Article) | OSTI.GOV … GOV Journal Article: Steric and electronic effects of
ligand substitution on redox-active Fe[subscript 4]S[subscript 4]-b Steric and electronic
effects of ligand substitution on redox-active Fe[subscript 4]S[subscript 4]-b …
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