Study of hydrogen bonding and thermodynamic behavior in water–1, 4-dioxane mixture using time domain reflectometry
AC Kumbharkhane, YS Joshi, SC Mehrotra… - Physica B: Condensed …, 2013 - Elsevier
A picosecond time domain reflectometry (TDR) technique was used to measure complex
permittivity of water–dioxane mixtures in frequency range of 10–30GHz covering entire
concentrations range and in temperature range of 0–25° C. The Luzar theoretical model is
used to compute the binding energies and average number of hydrogen bond for water–
water and water–dioxane molecules. The number of hydrogen bond density is found to be
maximum for the mixture with water concentration Xw= 0.7. The negative values of the …
permittivity of water–dioxane mixtures in frequency range of 10–30GHz covering entire
concentrations range and in temperature range of 0–25° C. The Luzar theoretical model is
used to compute the binding energies and average number of hydrogen bond for water–
water and water–dioxane molecules. The number of hydrogen bond density is found to be
maximum for the mixture with water concentration Xw= 0.7. The negative values of the …
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