Synthesis and characterization of a novel Ca-alginate-biochar composite as efficient zinc (Zn2+) adsorbent: Thermodynamics, process design, mass transfer and …
Separation Science and Technology, 2019•Taylor & Francis
In this present work, Ca-alginate-biochar adsorbent has been synthesized, characterized
and tested its effectiveness in the removal of aqueous phase Zn2+ metal. The removal
efficiency was studied under various physicochemical process parameters. External mass
transfer model, intraparticle diffusion model and pseudo-first-order and pseudo-second-
order models were used to fit the experimental Zn2+ adoption kinetic results and to identify
the mechanism of adsorption. The desorption studies indicate the possibilities of ion …
and tested its effectiveness in the removal of aqueous phase Zn2+ metal. The removal
efficiency was studied under various physicochemical process parameters. External mass
transfer model, intraparticle diffusion model and pseudo-first-order and pseudo-second-
order models were used to fit the experimental Zn2+ adoption kinetic results and to identify
the mechanism of adsorption. The desorption studies indicate the possibilities of ion …
Abstract
In this present work, Ca-alginate-biochar adsorbent has been synthesized, characterized and tested its effectiveness in the removal of aqueous phase Zn2+ metal. The removal efficiency was studied under various physicochemical process parameters. External mass transfer model, intraparticle diffusion model and pseudo-first-order and pseudo-second-order models were used to fit the experimental Zn2+ adoption kinetic results and to identify the mechanism of adsorption. The desorption studies indicate the possibilities of ion-exchange and physical–chemical adsorption of Zn2+. The adsorption was best described by Langmuir isotherm model. Thermodynamic parameters suggested that the adsorption process becomes spontaneous, endothermic and irreversible in nature.
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