Synthesis and characterization of radial oligothiophenes: a new class of thiophene-based conjugated homologues

TM Pappenfus, KR Mann - Organic Letters, 2002 - ACS Publications
Organic Letters, 2002ACS Publications
A series of thiophene-based homologues with an aromatic core surrounded by terthiophene
“arms” with acetylene linkages has been synthesized by using Sonogashira coupling
methods. The homologues were investigated spectroscopically in solution and in the solid
state. They display extended π-conjugation through the aromatic core that affects the strong
emission and redox properties.
A series of thiophene-based homologues with an aromatic core surrounded by terthiophene “arms” with acetylene linkages has been synthesized by using Sonogashira coupling methods. The homologues were investigated spectroscopically in solution and in the solid state. They display extended π-conjugation through the aromatic core that affects the strong emission and redox properties.
ACS Publications
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