Structure of Mg-and Mg/Ca aluminosilicate glasses: 27Al NMR and Raman spectroscopy investigations

DR Neuville, L Cormier, V Montouillout… - American …, 2008 - degruyter.com
… In this paper, we present new results using Raman spectroscopy and 27Al nuclear magnetic
resonance on MAS and CMAS glasses. We propose an Al/Si tetrahedral distribution in the …

Synthesis and spectroscopic 27Al NMR and Raman characterization of new materials based on the assembly of [AlO4Al12 (OH) 24 (H2O) 12] 7+ isopolycation and Co …

M Muñoz, CI Cabello, IL Botto, G Minelli… - Journal of Molecular …, 2007 - Elsevier
… These new materials were characterized by X-ray powder diffraction (XRD), 27 Al nuclear
magnetic resonance (NMR); vibrational (FT-IR and Raman Microprobe) and UV–visible diffuse …

Quantitative studies on the microstructure of ternary CaO–Al2O3–SiO2 glasses by Raman spectroscopy, 27Al MAS NMR and quantum chemistry ab initio calculation

X Tang, J You, J Wang, F Zhang, X Gong, Y Xie… - Ceramics …, 2023 - Elsevier
characteristics of CaO–SiO 2 -based glassy samples with various Al 2 O 3 contents were
examined quantitatively by Raman spectroscopy and 27 Al MAS NMR. A … , and Raman spectral

Amorphous materials: Properties, structure, and durability: Structure of Mg- and Mg/Ca aluminosilicate glasses: 27Al NMR and Raman spectroscopy investigations

DR Neuville, L Cormier, V Montouillout… - American …, 2008 - degruyter.com
… In this paper, we present new results using Raman spectroscopy and 27Al nuclear magnetic
resonance on MAS and CMAS glasses. We propose an Al/Si tetrahedral distribution in the …

Raman and 27Al NMR structure investigations of aluminate glasses:(1− x) Al2O3− x MO, with M= Ca, Sr, Ba and 0.5< x< 0.75

M Licheron, V Montouillout, F Millot… - Journal of non-crystalline …, 2011 - Elsevier
… Using Raman spectroscopy and high field 27 Al NMR spectroscopy, we have determined …
In the SrO–Al 2 O 3 system, we synthesized glasses between 55% and 75% of SrO. And finally, …

Al coordination and speciation in calcium aluminosilicate glasses: Effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy

DR Neuville, L Cormier, D Massiot - Chemical geology, 2006 - Elsevier
… Millot (CRMHT CNRS) for their help in the synthesis of several of the glasses used in this
study; H. Forster, S. Steuernagel and Bruker Karlsruhe for acquisition of 750 MHz …

A new aluminium-hydrate species in hydrated Portland cements characterized by 27Al and 29Si MAS NMR spectroscopy

MD Andersen, HJ Jakobsen, J Skibsted - Cement and Concrete Research, 2006 - Elsevier
… We note that the quantitative 27 Al MAS NMR analysis of C1_H hydrated for 30 weeks gives
the … = 1.00 sample but excluded either Ca(OH) 2 or SiO 2 from the synthesis mixture. The …

Al environment in tectosilicate and peraluminous glasses: A 27Al MQ-MAS NMR, Raman, and XANES investigation

DR Neuville, L Cormier, D Massiot - Geochimica et Cosmochimica Acta, 2004 - Elsevier
… using Raman spectroscopy, X-ray absorption at the Al K-edge and 27 Al NMR spectroscopy
… from pure SiO 2 to calcium aluminate can be synthesized using normal quench rate (10/s), …

Transitions in Al Coordination during Gibbsite Crystallization Using High-Field 27Al and 23Na MAS NMR Spectroscopy

JZ Hu, X Zhang, NR Jaegers, C Wan… - The Journal of …, 2017 - ACS Publications
… 72 h (Figure 3e), the yield of this material surpassed 80%. We demonstrate that the XRD
pattern of the synthesized gibbsite is well-fit by simulated curves using the standard powder …

Combining 27Al Solid-State NMR and First-Principles Simulations To Explore Crystal Structure in Disordered Aluminum Oxynitride

B Tu, X Liu, H Wang, W Wang, P Zhai, Z Fu - Inorganic Chemistry, 2016 - ACS Publications
… and 9.7 ppm are shown in our 27 Al MAS NMR spectra at 11.7 T, which obviously originate
… Figure 3 also presents the curves obtained from fitting the 27 Al MAS NMR spectra. This two-…