Synthesis of P (O)-S organophosphorus compounds by dehydrogenative coupling reaction of P (O) H compounds with aryl thiols in the presence of base and air
The synthesis method of P (O)-S organophosphorus compounds by dehydrogenative
coupling reaction of P (O) H compounds and aryl thiols was developed. The reaction was
carried in the presence of a base and air, and exhibited good characters such as metal-free,
mild reaction temperature, excellent substrate tolerance and with moderate to good yields. A
plausible mechanism was proposed.
coupling reaction of P (O) H compounds and aryl thiols was developed. The reaction was
carried in the presence of a base and air, and exhibited good characters such as metal-free,
mild reaction temperature, excellent substrate tolerance and with moderate to good yields. A
plausible mechanism was proposed.
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