Temperature dependence electrical conduction of solution-processed CZTS films in dark and under light

PR Ghediya, TK Chaudhuri… - IOP Conference Series …, 2016 - iopscience.iop.org
PR Ghediya, TK Chaudhuri, KC Patel
IOP Conference Series: Materials Science and Engineering, 2016iopscience.iop.org
Electrical conduction of solution-processed Cu 2 ZnSnS 4 (CZTS) films has been reported in
dark and under light in the temperature range of 85 to 300 K. The films show nearest
neighbor hopping mode of transport at below 200 K, while above 200 K the films were
dominated by thermionic emission over grain boundary barriers, following, Seto's model for
polycrystalline films. The hopping energy and grain boundary barrier height of CZTS films
are found be decreases under illumination due to the photoconductivity. The films were pure …
Abstract
Electrical conduction of solution-processed Cu 2 ZnSnS 4 (CZTS) films has been reported in dark and under light in the temperature range of 85 to 300 K. The films show nearest neighbor hopping mode of transport at below 200 K, while above 200 K the films were dominated by thermionic emission over grain boundary barriers, following, Seto's model for polycrystalline films. The hopping energy and grain boundary barrier height of CZTS films are found be decreases under illumination due to the photoconductivity. The films were pure kesterite CZTS as revealed from X-Ray diffraction and Raman spectroscopy.
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