The absorption spectrum of CH3I in the extreme VUV
G O'Sullivan - Journal of Physics B: Atomic and Molecular …, 1982 - iopscience.iop.org
Journal of Physics B: Atomic and Molecular Physics, 1982•iopscience.iop.org
The absorption spectrum of methyl iodide has been photographed in the wavelength region
80-270 AA. Photoexcitation of the iodine 4d subshell was found to dominate the spectrum,
giving rise to discrete 1 A 1 to 1 A 1, 1 E transitions and a giant 4d to epsilon f continuum
resonance. An analysis of the transitions is given and a value of 1.72+ or-0.05 eV deduced
for the 4d 3 2/-4d 5/2 spin-orbit splitting in the iodine atom.
80-270 AA. Photoexcitation of the iodine 4d subshell was found to dominate the spectrum,
giving rise to discrete 1 A 1 to 1 A 1, 1 E transitions and a giant 4d to epsilon f continuum
resonance. An analysis of the transitions is given and a value of 1.72+ or-0.05 eV deduced
for the 4d 3 2/-4d 5/2 spin-orbit splitting in the iodine atom.
Abstract
The absorption spectrum of methyl iodide has been photographed in the wavelength region 80-270 AA. Photoexcitation of the iodine 4d subshell was found to dominate the spectrum, giving rise to discrete 1 A 1 to 1 A 1, 1 E transitions and a giant 4d to epsilon f continuum resonance. An analysis of the transitions is given and a value of 1.72+ or-0.05 eV deduced for the 4d 3 2/-4d 5/2 spin-orbit splitting in the iodine atom.
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