The microwave spectrum and structure of KrAgF
NR Walker, LM Reynard, MCL Gerry - Journal of molecular structure, 2002 - Elsevier
The microwave spectrum of KrAgF has been assigned between 8–18GHz, using a cavity
pulsed-jet Fourier transform microwave spectrometer. The structure of the molecule has
been calculated from the measured rotational constants of four isotopomers. Values for the
Kr–Ag and Ag–F bond lengths of∼ 2.594 and∼ 1.957 Å respectively have been
determined. A small centrifugal distortion constant (∼ 0.3 kHz) indicates that the molecule is
comparatively rigid. The stretching frequency and dissociation energy of the Kr–Ag bond …
pulsed-jet Fourier transform microwave spectrometer. The structure of the molecule has
been calculated from the measured rotational constants of four isotopomers. Values for the
Kr–Ag and Ag–F bond lengths of∼ 2.594 and∼ 1.957 Å respectively have been
determined. A small centrifugal distortion constant (∼ 0.3 kHz) indicates that the molecule is
comparatively rigid. The stretching frequency and dissociation energy of the Kr–Ag bond …
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