The Myth of d8 Copper(III)

IM DiMucci, JT Lukens, S Chatterjee… - Journal of the …, 2019 - ACS Publications
… physical d 8 description for these formally Cu III species is inaccurate. This study … Cu III
species in transformations that are traditionally described as metal-centered, 2-electron Cu I /Cu III

Copper–Carbon Homolysis Competes with Reductive Elimination in Well-Defined Copper (III) Complexes

W Yan, S Carter, CT Hsieh, JA Krause… - Journal of the …, 2023 - ACS Publications
… In this work, we present the synthesis and exploration of alkyl–Cu III complexes that can
exclusively undergo Cu III –C homolytic cleavage reactions to form alkyl radicals and Cu II

Copper dithiocarbamates: coordination chemistry and applications in materials science, biosciences and beyond

G Hogarth, DC Onwudiwe - Inorganics, 2021 - mdpi.com
… CuCl 2 addition to [Cu(S 2 CNEt 2 ) 2 ] is [Cu 3 (S 2 CNEt 2 )Cl 3 ], a mixed-… Cu(II) and
tetrahedral Cu(I) centres. The addition of CuX 2 (X = Cl, Br) to [Cu(S 2 CNC 5 H 10 ) 2 ] in CHCl 3 /…

Combining valence-to-core x-ray emission and Cu k-edge x-ray absorption spectroscopies to experimentally assess oxidation state in organometallic Cu (I)/(II)/(III) …

…, F Meyer, S DeBeer, GE Cutsail III - Journal of the …, 2022 - ACS Publications
… The newly synthesized Cu(III) cation [Cu III (NHC 4 )] 3+ … , but in [Cu II (NHC 2 )] 2+ and [Cu
III (NHC 2 )] 3+ an acetonitrile … [Cu III (NHC 4 )] 3+ is closely related to [Cu III (NHC 2 )] 3+ , but …

Identifying the Local Atomic Environment of the “Cu3+” State in Alkaline Electrochemical Systems

L Ostervold, R Daneshpour, M Facchinei… - … Applied Materials & …, 2023 - ACS Publications
Cu 3+ , but the reader should note that the reference to Cu 3+ retains the noncommittal
correlation between this notation and the actual local electronic structure about Cu … possible Cu 3

Cu (II), Co (II), Mn (II) complexes with 5-phenyltetrazole and polypyridyl ligands: Synthesis, characterization and evaluation of the cytotoxicity and antimicrobial activity

JA Eremina, EA Ermakova, KS Smirnova… - Polyhedron, 2021 - Elsevier
In this work, six new mixed-ligand Cu(II), Co(II), Mn(II) complexes with 5-phenyltetrazole (HL)
and polypyridine ligands (phen – 1,10-phenanthroline, dmbipy – 2,2′-bi-4-picoline, …

Synthesis and characterization of copper (II) complexes containing acetate and N, N-donor ligands, and their electrochemical behavior in dopamine detection

AP Sandoval-Rojas, L Ibarra, MT Cortés… - Journal of …, 2017 - Elsevier
… of Cu(II) for DA. We have recently reported the synthesis of cobalt and copper(II) complexes
bearing bis(3,… structural characterization of mononuclear Cu(II) complexes containing bis(3,5-…

C–N Bond Formation at Discrete CuIII–Aryl Complexes

MS Reese, MG Bonanno, JK Bower… - Journal of the …, 2023 - ACS Publications
… Despite their wide utility, mechanistic aspects of C-heteroatom formation at Cu III centers …
Cu III –Ar complexes. Herein, we report the synthesis and reactivity of a series of Cu II and Cu III

Oxidative Substitution of Organocopper (II) by a Carbon-Centered Radical

Y Weng, Y Jin, J Wu, X Leng, X Lou… - Journal of the …, 2024 - ACS Publications
… [C 16 H 11 CuF 3 N 3 ] + , corresponding to [(tpy)Cu II (CF 3 )] + (… Cu II (CF 3 )] + is attributed
to dissociation of a CF 3 ligand in the possible organocopper(II) intermediate [(tpy)Cu II (CF 3

Spectral Physics of Stable Cu (III) Produced by Oxidative Addition of an Alkyl Halide

E Cao, M Sun - International Journal of Molecular Sciences, 2023 - mdpi.com
… and neutral Cu(I) and two kinds of products of Cu(III) … and resonance Raman spectra of two
Cu(III) complexes. The nuclear … also to distinguish between two Cu(III) complexes. The charge …