Thermal initiation and propagation of the decomposition process

R Claveau, J Glorian, D Mathieu - Theoretical and Computational …, 2022 - Elsevier
This chapter reviews sensitivity correlations assuming initiation to be thermal in nature. A
first group focuses on the thermal onset of chemistry, either considering only the first bond
breaking events or accounting for more details of the mechanism. A second group assigns a
prominent role to the propagation of the decomposition. Finally, a two-states model
predicting the initiation probability as a function of the magnitude of the load is outlined.
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