Total synthesis of taiwaniadducts B, C, and D

J Deng, S Zhou, W Zhang, J Li, R Li… - Journal of the American …, 2014 - ACS Publications
… We first undertook a retrosynthetic analysis of taiwaniadduct D (1), as illustrated in Scheme
1. The initial disconnection takes place at the C6–C14′ bond to provide taiwaniadduct B (2) …

Convergent strategies in total syntheses of complex terpenoids

D Urabe, T Asaba, M Inoue - Chemical Reviews, 2015 - ACS Publications
… (7) Since many excellent reviews have been published for these biomimetic syntheses, (8,
9) this review focuses on the nonbiomimetic strategies for the total synthesis of terpenoids. …

Total synthesis of natural products via iridium catalysis

C Yuan, B Liu - Organic Chemistry Frontiers, 2018 - pubs.rsc.org
… ester to furnish taiwaniadducts C and B (314 and 315), respectively. Subsequently,
carbonyl–ene cyclization of 315 promoted by Me 2 AlCl led to taiwaniadduct D (316, Scheme 35). …

Total Synthesis of Four Classes of Daphniphyllum Alkaloids

W Zhang, M Lu, L Ren, X Zhang, S Liu… - Journal of the …, 2023 - ACS Publications
… Taking advantage of a protocol (Na 2 CO 3 (aq), MeOH, 100 C) modified from that
developed for our synthesis of hybridaphniphylline B, (7) we obtained ketone 26 as a single C8 …

Diels–Alder Reactions in Creating Complexity in Higher Order Isoprenoids: Proposed Biosynthesis and Biomimetic Total Syntheses

V Bisai, A Bisai - Asian Journal of Organic Chemistry, 2018 - Wiley Online Library
… Li and co-workers have accomplished the first total synthesis of taiwaniadducts B (72), C (73),
and D (75), where an Ir-catalyzed asymmetric polyene cyclization was exploited to …

Direct construction of vicinal all-carbon quaternary stereocenters in natural product synthesis

R Long, J Huang, J Gong, Z Yang - Natural Product Reports, 2015 - pubs.rsc.org
… been successfully used in the total synthesis of natural products. … Taiwaniadducts B, C, and
D. Taiwaniaquinoids are a class of … From a biosynthetic perspective, taiwaniadduct D (37, …

Synthesis of Taiwaniadducts B, C, and D

EM Carreira, N Huwyler - Synfacts, 2014 - thieme-connect.com
… The first asymmetric total syntheses of taiwaniadducts B, C, and D, isolated from the Taiwanese
evergreen tree Taiwania cryptomeriodes, are reported. Biosynthetically these molecules …

Enantioselective polyene cyclizations

CN Ungarean, EH Southgate, D Sarlah - Organic & Biomolecular …, 2016 - pubs.rsc.org
… The LBA strategy has found use in the total synthesis of … cyclization in natural product
synthesis was demonstrated by … form taiwaniadduct C (141) and its regioisomer taiwaniadduct B

Asymmetric total synthesis of arcutinidine, arcutinine, and arcutine

S Zhou, K Xia, X Leng, A Li - Journal of the American Chemical …, 2019 - ACS Publications
… In summary, we have accomplished the asymmetric total synthesis of arcutinidine (3),
arcutinine (2), and arcutine (25). An expeditious and scalable route to a pentacyclic intermediate …

Total syntheses of (±)-taiwaniaquinol D and (±)-taiwaniaquinone D via a key Lewis acid-catalyzed Nazarov type cyclization

BN Kakde, A Parida, P Kumari, A Bisai - Tetrahedron Letters, 2016 - Elsevier
… Recently our group has also reported total synthesis of taiwaniaquinoids with various … for
synthetic approaches to complex taiwaniadducts B (2a) and taiwaniadduct F (2b) sharing all-…