Toward asymmetric aziridination with an iron complex supported by a D 2-symmetric tetra-NHC
KM Blatchford, CJ Mize, S Roy, DM Jenkins - Dalton Transactions, 2022 - pubs.rsc.org
KM Blatchford, CJ Mize, S Roy, DM Jenkins
Dalton Transactions, 2022•pubs.rsc.orgA neutral D2-symmetric macrocyclic tetra-N-heterocyclic carbene ligand was synthesized.
The macrocycle was ligated to iron (II) via transmetalation from an isolated silver complex
that has two conformers. The iron complex catalyzed the first stereospecific aziridination
between aryl azides and aliphatic alkenes, albeit with low ee's.
The macrocycle was ligated to iron (II) via transmetalation from an isolated silver complex
that has two conformers. The iron complex catalyzed the first stereospecific aziridination
between aryl azides and aliphatic alkenes, albeit with low ee's.
A neutral D2-symmetric macrocyclic tetra-N-heterocyclic carbene ligand was synthesized. The macrocycle was ligated to iron(II) via transmetalation from an isolated silver complex that has two conformers. The iron complex catalyzed the first stereospecific aziridination between aryl azides and aliphatic alkenes, albeit with low ee's.
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