Towards the total synthesis of colletofragarones: constructing the macrocyclic lactone by high pressure-mediated intramolecular Diels–Alder reaction
JG Marrero, LM Harwood - Tetrahedron Letters, 2009 - Elsevier
We report herein an intramolecular Diels–Alder approach towards the construction of the
macrocyclic lactone ring and the perhydrobenzofuran system of the colletofragarones, novel
metabolites produced by fungi of the genus Colletotrichum that are responsible for inhibition
of germination of the conidia in these species.
macrocyclic lactone ring and the perhydrobenzofuran system of the colletofragarones, novel
metabolites produced by fungi of the genus Colletotrichum that are responsible for inhibition
of germination of the conidia in these species.
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