Unraveling the Near-Unity Narrow-Band Green Emission in Zero-Dimensional Mn2+-Based Metal Halides: A Case Study of (C10H16N)2Zn1–xMnxBr4 Solid …
G Zhou, Z Liu, J Huang, MS Molokeev… - The Journal of …, 2020 - ACS Publications
Zero-dimensional (0D) Mn2+-based metal halides are potential candidates as narrow-band
green emitters, and thus it is critical to provide a structural understanding of the
photophysical process. Herein, we propose that a sufficiently long Mn–Mn distance in 0D
metal halides enables all Mn2+ centers to emit spontaneously, thereby leading to near-unity
photoluminescence quantum yield. Taking lead-free (C10H16N) 2Zn1–x Mn x Br4 (x= 0–1)
solid solution as an example, the Zn/Mn alloying inhibits the concentration quenching that is …
green emitters, and thus it is critical to provide a structural understanding of the
photophysical process. Herein, we propose that a sufficiently long Mn–Mn distance in 0D
metal halides enables all Mn2+ centers to emit spontaneously, thereby leading to near-unity
photoluminescence quantum yield. Taking lead-free (C10H16N) 2Zn1–x Mn x Br4 (x= 0–1)
solid solution as an example, the Zn/Mn alloying inhibits the concentration quenching that is …
[引用][C] Unraveling the Near-Unity Narrow-Band Green Emission in Zero-Dimensional Mn2+-Based Metal Halides: A Case Study of (C10H16N) 2Zn1-xMnxBr4 Solid …
Z Guojun, L Zhiyang, H Jinglong, MS Molokeev… - 2020 - elib.sfu-kras.ru
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