Biosorption is considered one of the most promising methods for removal of metal ions from aqueous effluents, due to its low-cost and eco-friendly characteristics. However, the exhausted biosorbents loaded with metal ions, obtained at the end of biosorption processes, are still a problem which should be solved to increase the applicability of biosorption on an industrial scale. In this study are examined three possibilities for the valorisation of exhausted biosorbents loaded with metal ions, namely: (i) regeneration and reuse of biosorbents in multiple biosorption cycles, (ii) the use of exhausted biosorbents as fertilizers for soils poor in essential microelements, and (iii) the pyrolysis of exhausted biosorbents, under well defined conditions. The main advantages and disadvantages of each valorisation possibility are reviewed in order to find the best way to use these cheap materials in accordance with the principles of the circular economy and thereby contributing to the development of sustainable biosorption technology.