WTe2 Synthesis by Tellurization of W Precursors Using Isothermal Close Space Vapor Transport Annealing

O de Melo, M Sánchez, A Borroto… - … status solidi (a), 2018 - Wiley Online Library
physica status solidi (a), 2018Wiley Online Library
The preparation of WTe2 by isothermal tellurium annealing of sputtered W or WO3
precursors is reported. X‐ray diffraction, energy dispersive, and Raman spectroscopies
confirm the presence of 1T́ WTe2 phase in the annealed films which are preferentially
oriented with the [001] crystallographic direction normal to the surface. Atomic force
microscopy images indicate noticeable morphology differences between thin samples
tellurized from different precursors. Rounded small grains or small platelets are obtained …
The preparation of WTe2 by isothermal tellurium annealing of sputtered W or WO3 precursors is reported. X‐ray diffraction, energy dispersive, and Raman spectroscopies confirm the presence of 1T́ WTe2 phase in the annealed films which are preferentially oriented with the [001] crystallographic direction normal to the surface. Atomic force microscopy images indicate noticeable morphology differences between thin samples tellurized from different precursors. Rounded small grains or small platelets are obtained when W and WO3 precursor are used, respectively.
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