Water-soluble iridium and rhodium complexes with tris (hydroxymethyl) phosphine and their catalysis in biphasic hydrogenation and hydroformylation
Chemical Communications, 1999•pubs.rsc.org
… Novel water-soluble Ir and Rh complexes with tris(hydroxymethyl)phosphine catalyse the
selective hydrogenation of the CNO bond of cinnamaldehyde and the hydroformylation of
pent-1-ene both under biphasic conditions. … 5a Recently, Pringle and coworkers showed high
efficiency of THMP complexes of Pt, Pd and Ni in catalytic hydrophosphination of
formaldehyde,6 and biphasic hydrogenation of sorbic acid was reported using THMP complexes
of Ru.In this study, we have prepared novel THMP complexes of Ir and Rh, and their catalytic …
selective hydrogenation of the CNO bond of cinnamaldehyde and the hydroformylation of
pent-1-ene both under biphasic conditions. … 5a Recently, Pringle and coworkers showed high
efficiency of THMP complexes of Pt, Pd and Ni in catalytic hydrophosphination of
formaldehyde,6 and biphasic hydrogenation of sorbic acid was reported using THMP complexes
of Ru.In this study, we have prepared novel THMP complexes of Ir and Rh, and their catalytic …
Novel water-soluble Ir and Rh complexes with tris(hydroxymethyl)phosphine catalyse the selective hydrogenation of the CO bond of cinnamaldehyde and the hydroformylation of pent-1-ene both under biphasic conditions.
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