Zr-MOFs–catalyzed transfer hydrogenation of furfural to furfuryl alcohol: Unveiled performance of DUT-52
KD Agusta, MF Miharja, AW Sakti, USF Arrozi… - Molecular …, 2022 - Elsevier
Catalytic transfer hydrogenation (CTH) of 2-furfuraldehyde (FALD) at 1 atm has potential
industrial applications to produce furfuryl alcohol (FOL) and its derivatives mildly. The
process was explored using alcohols in the absence of H 2. Solvothermally prepared
zirconium (IV) metal organic frameworks (Zr-MOFs) of DUT-52 (DUT: Dresden University of
Technology) and UiO-66 (UiO: University of Oslo) were employed in the CTH. Energetic
studies (GFN2-xTB level) revealed a similar Gibbs free energy of DUT-52 and UiO-66 when …
industrial applications to produce furfuryl alcohol (FOL) and its derivatives mildly. The
process was explored using alcohols in the absence of H 2. Solvothermally prepared
zirconium (IV) metal organic frameworks (Zr-MOFs) of DUT-52 (DUT: Dresden University of
Technology) and UiO-66 (UiO: University of Oslo) were employed in the CTH. Energetic
studies (GFN2-xTB level) revealed a similar Gibbs free energy of DUT-52 and UiO-66 when …
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