Cu2O nanocubes with mixed oxidation-state facets for (photo)catalytic hydrogenation of carbon dioxide

L Wan, Q Zhou, X Wang, TE Wood, L Wang… - Nature Catalysis, 2019 - nature.com
… There are many faces to the story of how Cu 2 O nanocubes enable the photocatalytic
hydrogenation of CO 2 . Indeed, with surfaces comprising mixed copper oxidation states, oxygen …

Importance of the initial oxidation state of copper for the catalytic hydrogenation of dimethyl oxalate to ethylene glycol

Y Sun, F Meng, Q Ge, J Sun - ChemistryOpen, 2018 - Wiley Online Library
… the initial oxidation state of copper and the activity of the catalyst to provide a reference for
further exploration of the mechanism and guidance for the design of hydrogenation catalysts. …

Highly active and selective manganese C= O bond hydrogenation catalysts: the importance of the multidentate ligand, the ancillary ligands, and the oxidation state

F Kallmeier, T Irrgang, T Dietel… - Angewandte Chemie …, 2016 - Wiley Online Library
… of the PN 5 P ligand, the right oxidation state of the metal, and the right … catalytic activity.
Parallel to our work, Beller and co-workers introduced a Mn catalyst for C=O bond hydrogenation

Catalytic hydrogenation of carbon oxides–a 10-year perspective

Y Borodko, GA Somorjai - Applied Catalysis A: General, 1999 - Elsevier
hydrogenation route over palladium-based systems. The oxide–metal interface sites are often
better catalysts … the Lewis acidity of certain high oxidation state transition metal oxides that …

Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects

BR Cuenya - Thin Solid Films, 2010 - Elsevier
… a broad range of catalytic processes. As a … catalysis, including the role played by the
particle structure and morphology (size and shape), its chemical composition and oxidation state

The role of copper oxidation state in Cu/ZnO/Al2O3 catalysts in CO2 hydrogenation and methanol productivity

VDBC Dasireddy, B Likozar - Renewable Energy, 2019 - Elsevier
… alkaline moieties was found analogous to all catalysts studied. Cu + /Cu 0 oxidation state
role and distribution may, therefore, aid in CO 2 conversion catalyst design and optimisation. …

Correlation between metal oxidation state and catalytic activity: hydrogenation of crotonaldehyde over Rh catalysts

P Ferreira-Aparicio, B Bachiller-Baeza… - Catalysis letters, 1997 - Springer
… The effects of the rhodium (oxidation) state on the activity and selectivity for the crotonaldehyde
hydrogenation reaction over Rh/Al2O3 and Rh/SiO2 catalysts were examined using the …

Distribution of molybdenum oxidation states in reduced molybdenum/alumina catalysts: correlation with benzene hydrogenation activity

M Yamada, J Yasumaru, M Houalla… - The Journal of …, 1991 - ACS Publications
… of the reduction of Mo/A1203 catalysts by ESCA. This study will include … oxidation states
in H2-reduced Mo/A1203 catalysts by ESCA; (b) correlation of the average Mo oxidation state

Heterogeneous catalytic hydrogenation of CO 2 by metal oxides: defect engineering–perfecting imperfection

J Jia, C Qian, Y Dong, YF Li, H Wang… - Chemical Society …, 2017 - pubs.rsc.org
… can be tuned by the nature of the metal site, control being related to the size, charge,
coordination number, geometry and electronegativity of the metal in a particular oxidation state. …

Oxidation state of germanium promoter on a palladium/carbon catalyst and its role in hydrogenation reactions

Z Bodnar, T Mallat, I Bakos, S Szabo, Z Zsoldos… - Applied Catalysis A …, 1993 - Elsevier
oxidation state and location of germanium promoter in a carbon-supported palladium catalyst
… of the open circuit potential of the catalyst slurry revealed that the increase in the oxidation