Plasmon-generated hot holes for chemical reactions

C Zhang, F Jia, Z Li, X Huang, G Lu - Nano Research, 2020 - Springer
… of these hot holes in redox reactions is … reactions involving the plasmon-generated hot
holes and expanding the applications of these hot holes in varieties of chemical reactions, …

From optical to chemical hot spots in plasmonics

J Gargiulo, R Berté, Y Li, SA Maier… - Accounts of chemical …, 2019 - ACS Publications
chemical reaction. (41) We combined dark-field microscopy with an electrochemical setup to
study a plasmonic hot-hole-driven reaction … the hot-holes energy contribution to the reaction

Direct detection of electron–hole pairs generated by chemical reactions on metal surfaces

H Nienhaus, HS Bergh, B Gergen, A Majumdar… - Surface science, 2000 - Elsevier
hot electron and hot holechemical and intrinsic diode properties influence the magnitude
of the chemicurrent and if the effect is universal, ie if chemicurrents are detectable with reaction

Electronic excitations by chemical reactions on metal surfaces

H Nienhaus - Surface Science Reports, 2002 - Elsevier
… ultrathin metal films makes direct measurement of reaction-induced hot electrons and holes
possible. The chemical reaction creates hot charge carriers which travel ballistically from the …

Spectral screening of the energy of hot holes over a particle plasmon resonance

E Pensa, J Gargiulo, A Lauri, S Schlücker… - Nano Letters, 2019 - ACS Publications
… carriers and surface temperature) can provide a quanta of energy to induce a chemical
reaction at milder conditions compared to the non-illuminated nanostructure. (3−6) At the same …

Using hot electrons and hot holes for simultaneous cocatalyst deposition on plasmonic nanostructures

E Kontoleta, A Tsoukala, SHC Askes… - … applied materials & …, 2020 - ACS Publications
… is the result of a hot hole rather than a purely thermal or chemical reaction mechanism. Au
nanoislands are a very good system to monitor the hot-hole chemical reaction due to the high …

Plasmon-induced hot-hole generation and extraction at nano-heterointerfaces for photocatalysis

M Ahlawat, D Mittal, V Govind Rao - Communications Materials, 2021 - nature.com
… adopted to extract hot holes from the plasmonic metals. Further, we will review the
advancements in plasmonic catalysis, highlighting hot holes driven chemical reactions and their …

Surface reactions with hot electrons and hot holes in metals

D Diesing, H Janssen, A Otto - Surface science, 1995 - Elsevier
… , respectively, at electrochemical potentials where no reactions occur with the electrode in
its … by intermediate hot electrons. In the present work hot electrons and hot holes are injected …

Hot holes assist plasmonic nanoelectrode dissolution

A Al-Zubeidi, BS Hoener, SSE Collins, W Wang… - Nano …, 2019 - ACS Publications
hot holes from interband transitons are more efficient at photoassisted electrodissolution
than warm holes … they establish that hot d-band holes are able to participate in chemical

Hot‐electron‐mediated photochemical reactions: principles, recent advances, and challenges

M Kim, M Lin, J Son, H Xu… - Advanced Optical Materials, 2017 - Wiley Online Library
… in hot electron effect-mediated chemical reactions from the … how the hot electron effect
mediates chemical reactions and how … In silver, the hot holes and hot electrons share comparable …