Efficient tuning of surface copper species of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol

Y Zhao, S Li, Y Wang, B Shan, J Zhang, S Wang… - Chemical Engineering …, 2017 - Elsevier
copper species of Cu/SiO 2 catalysts for DMO hydrogenation. … reveal the origin of the catalytic
performances. Compared to the … dispersion of copper species and large ratio of Cu + /(Cu + …

The Nature of Active Copper Species in Cu-HMS Catalyst for Hydrogenation of Dimethyl Oxalate to Ethylene Glycol: New Insights on the Synergetic Effect between Cu0 and Cu …

A Yin, X Guo, WL Dai, K Fan - The Journal of Physical Chemistry …, 2009 - ACS Publications
… higher copper oxide speciescatalyst that is highly efficient in the hydrogenation of dimethyl
oxalate (DMO) to ethylene glycol (EG). Special attention is paid to the effects of the copper

Deactivation of supported copper metal catalysts for hydrogenation reactions

MV Twigg, MS Spencer - Applied Catalysis A: General, 2001 - Elsevier
… -temperature water-gas shift catalysts is associated with zinc rather than copper species.(5)
Cu ( s … In practice, depending on the amount of water present, hydroxychloro species may be …

Recent progress in improving the stability of copper-based catalysts for hydrogenation of carbon–oxygen bonds

RP Ye, L Lin, Q Li, Z Zhou, T Wang… - Catalysis Science & …, 2018 - pubs.rsc.org
… deactivation and introduces five strategies for improving their stability, as well as the
evolution of copper species during preparation and reaction and a novel Cu-based …

Evidence for different copper species in precursors of copper–cerium oxide catalysts for hydrogenation reactions. An X-ray diffraction, EPR and X-ray photoelectron …

C Lamonier, A Bennani, A D'Huysser… - Journal of the …, 1996 - pubs.rsc.org
… the cerium-copper alloys and with mixed oxides based on copper associated with Cr, …
hydrogenation of unsaturated polyenes or CO has been studied in our laboratory.'-' As the catalytic

A Molecular Copper Catalyst for Hydrogenation of CO2 to Formate

CM Zall, JC Linehan, AM Appel - ACS Catalysis, 2015 - ACS Publications
… From the NMR spectra, the copper species converted from 1-MeCN to the inactive formate
complex, 1-O 2 CH, which precipitated. Thus, in addition to promoting the rates of reaction, …

The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation

H Zhao, R Yu, S Ma, K Xu, Y Chen, K Jiang, Y Fang… - Nature Catalysis, 2022 - nature.com
… report a copper-based catalyst with isolated active copper sites for the hydrogenation of CO
2 … This work reveals the strong dependence of CO 2 hydrogenation activity and selectivity on …

Copper Catalysts Unleashing the Potential for Hydrogenation of Carbon− Oxygen Bonds

R Watari, Y Kayaki - Asian Journal of Organic Chemistry, 2018 - Wiley Online Library
… homogeneous Cu catalysts have been intensively studied. In this Focus Review, we will
describe the hydrogenation of carbon−oxygen bonds catalyzed by copper-containing species. …

Insight into the synergism between copper species and surface defects influenced by copper content over copper/ceria catalysts for the hydrogenation of carbonate

H Li, Y Cui, Q Liu, WL Dai - ChemCatChem, 2018 - Wiley Online Library
… Almost no diffraction peak of any other phase of copper species can be observed at mass
loadings lower than 10 wt %, which suggests that too many copper species in the catalysts will …

Active sites and structure–activity relationships of copper-based catalysts for carbon dioxide hydrogenation to methanol

S Natesakhawat, JW Lekse, JP Baltrus… - Acs catalysis, 2012 - ACS Publications
… Therefore, the surface copper species of the working catalysts remain in the metallic state
under the experimental conditions used in this study as indicated by the KE values and shapes …