Promoting effect of boron oxide on Ag/SiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate

H Chen, J Tan, J Cui, X Yang, H Zheng, Y Zhu, Y Li - Molecular Catalysis, 2017 - Elsevier
A highly active and stable catalyst for the hydrogenation of dimethyl oxalate (DMO) to methyl
glycolate (MG) had been developed. The Ag-B 2 O 3 /SiO 2 catalysts were prepared by …

Selective Hydrogenation of Dimethyl Oxalate to Methyl Glycolate over Boron-Modified Ag/SiO2 Catalysts

S Cheng, T Meng, D Mao, X Guo, J Yu - ACS omega, 2022 - ACS Publications
… between the acidic boric oxide and the basic silver oxide. (30) … due to the higher electron
affinity of boric oxide than that of SiO 2 . … boric oxide and Ag species in the xB/Ag/SiO 2 catalysts. …

Effect of boric oxide doping on the stability and activity of a Cu–SiO2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol

Z He, H Lin, P He, Y Yuan - Journal of catalysis, 2011 - Elsevier
… steps: gasification of coal to syngas, catalytic coupling of CO with nitrite esters to dialkyl
oxalates such as dimethyl oxalate (DMO), and hydrogenation of oxalates to EG [4], [5], [6], [7]. …

Chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate on Cu/SiO2: Enhanced stability with boron dopant

S Zhao, H Yue, Y Zhao, B Wang, Y Geng, J Lv… - Journal of catalysis, 2013 - Elsevier
… The characterization of the catalysts shows that boron-modified … of copper particles during
dimethyl oxalate hydrogenation. … Thus, we deduce that boric oxide plays a very important role …

[HTML][HTML] Boron Modified Bifunctional Cu/SiO2 Catalysts with Enhanced Metal Dispersion and Surface Acid Sites for Selective Hydrogenation of Dimethyl Oxalate to …

D Yang, R Ye, L Lin, R Guo, P Zhao, Y Yin, W Cheng… - Nanomaterials, 2021 - mdpi.com
… there was an intense interaction between the support, copper oxide, and boron oxide
species [21]. With the increase of boron content, the copper species on the catalyst surface was …

A boron-doped carbon aerogel-supported Cu catalyst for the selective hydrogenation of dimethyl oxalate

X Lu, G Wang, Y Yang, X Kong, J Chen - New Journal of Chemistry, 2020 - pubs.rsc.org
boron-doped CA supports were systematically characterized and evaluated in the hydrogenation
of dimethyl oxalate (… facilely by changing the amount of boron doping, which effectively …

Boron-doped lamellar porous carbon supported copper catalyst for dimethyl oxalate hydrogenation

P Ai, L Zhang, J Niu, H Jin, W Huang - Chinese Journal of Chemical …, 2023 - Elsevier
Doping heteroatoms on carbon materials could bring some special advantages for using as
catalyst support. In this work, a boron doped lamellar porous carbon (B-LPC) was prepared …

Synergistic Effect of a Boron‐Doped Carbon‐Nanotube‐Supported Cu Catalyst for Selective Hydrogenation of Dimethyl Oxalate to Ethanol

P Ai, M Tan, N Yamane, G Liu, R Fan… - … A European Journal, 2017 - Wiley Online Library
… supported on boron-doped carbon nanotubes (Cu/xB-CNTs) were prepared for the
hydrogenation of dimethyl oxalate (DMO) to ethanol. The structure and chemical properties of boron-…

The influence of B-doping on the catalytic performance of Cu/HMS catalyst for the hydrogenation of dimethyloxalate

A Yin, J Qu, X Guo, WL Dai, K Fan - Applied Catalysis A: General, 2011 - Elsevier
Boron oxide is one of the additives that are widely used to modify textural and acid–base
properties of metal oxides, … Modifying copper species with boron introduces a very interesting …

A pentafluorophenylboron oxalate additive in non-aqueous electrolytes for lithium batteries

LF Li, HS Lee, H Li, XQ Yang, XJ Huang - Electrochemistry …, 2009 - Elsevier
… have boronboron-based compound with both BBAR and LiBOB function groups. In this
communication, we report the synthesis of pentafluorophenylboron oxalate (PFPBO), a new boron