In situ spectroscopic studies on vapor phase catalytic decomposition of dimethyl oxalate

S Hegde, K Tharpa, SR Akuri, K Rakesh… - Physical Chemistry …, 2017 - pubs.rsc.org
Dimethyl Oxalate (DMO) has recently gained prominence as a valuable intermediate for the
… The spectroscopy study is done at a temperature of 200 C, which is the onset of gas phase

Superior FeNi3-FeOx/Ni-foam catalyst for gas-phase hydrogenation of dimethyl oxalate to ethanol

J Zhu, G Zhao, W Sun, Q Nie, S Wang, Q Xue… - Applied Catalysis B …, 2020 - Elsevier
A high-performance Ni-foam-structured FeNi 3 -FeO x nanocomposite catalyst is developed
for the ethanol (EtOH) synthesis from syngas via gas-phase dimethyl oxalate (DMO) …

High-Performance Ni3P/meso-SiO2 for Gas-Phase Hydrogenation of Dimethyl Oxalate to Methyl Glycolate

G Zhao, H Li, J Si, Q Nie, C Meng, Y Liu… - … Sustainable Chemistry & …, 2021 - ACS Publications
Three meso-SiO 2 (RB-MSN, HMS, and MCM-41) supported Ni 3 P catalysts to be used in
gas-phase hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG) are prepared …

Highly-dispersed copper-based catalysts from Cu–Zn–Al layered double hydroxide precursor for gas-phase hydrogenation of dimethyl oxalate to ethylene glycol

S Zhang, Q Liu, G Fan, F Li - Catalysis letters, 2012 - Springer
The highly-dispersed copper-based catalysts for the gas-phase hydrogenation of dimethyl
oxalate to ethylene glycol (EG) were prepared from a Cu–Zn–Al layered double hydroxide (…

Molecular structure and infrared spectra of dimethyl oxalate

SB Lopes, L Lapinski, R Fausto - Physical Chemistry Chemical Physics, 2002 - pubs.rsc.org
… spectra observed in matrixes and in the gas phase, and the differences between these and
… IR spectra of crystalline dimethyl oxalate clearly show that in the relaxed crystal lattice only …

Hybrid modeling for carbon monoxide gas-phase catalytic coupling to synthesize dimethyl oxalate process

S Gao, C Bo, C Jiang, Q Zhang, G Yang… - Chinese Journal of …, 2024 - Elsevier
… The gas phase extracted from the top of the column enters the MN regeneration column. In …
the gas phase with other gas phase components as recycle gas, while the liquid phase enters …

Kinetics of reactions between methoxycarbonyl, methyl, and methoxy radicals formed in flash photolysis of dimethyl oxalate in gas phase

E Hassinen, P Riepponen, K Blomqvist… - … journal of chemical …, 1985 - Wiley Online Library
… acetate, dimethyl carbonate [41 and dimethyloxalate [51 were observed. We produced
methoxycarbonyl radicals by flash photolysis of dimethyl oxalate in gas phase and investigated …

Cu-fiber-structured La 2 O 3–PdAu (alloy)–Cu nanocomposite catalyst for gas-phase dimethyl oxalate hydrogenation to ethylene glycol

L Han, G Zhao, Y Chen, J Zhu, P Chen… - Catalysis Science & …, 2016 - pubs.rsc.org
… Therefore, one alternative route for EG production now arousing great interest is gas-phase
hydrogenation of dimethyl oxalate (DMO) which has achieved industrialized production of …

Vibrational spectra and structure of dimethyl oxalate and dimethyl oxalate-d6

JR Durig, SC Brown - Journal of Molecular Structure, 1976 - Elsevier
… The vibrational spectra of dimethyl oxalate-d, have been … of the spectra and structure of
dimethyl oxalate. The vibrational … phase and a non-planar Cz form in the liquid and gas phases. …

High-performance Ag-CuOx nanocomposite catalyst galvanically deposited onto a Ni-foam for gas-phase dimethyl oxalate hydrogenation to methyl glycolate

Y Chen, L Han, J Zhu, P Chen, S Fan, G Zhao… - Catalysis …, 2017 - Elsevier
gas-phase hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG). The best
catalyst 0.4-Ag-28-CuO x /Ni-foam was capable of converting more than 96% DMO into MG with …