A promising alternative potential solution for sustainable and economical development of coal to ethylene glycol industry: Dimethyl oxalate to methyl glycolate process

Q Yang, Y Fan, C Liu, J Zhou, L Zhao, H Zhou - Energy, 2023 - Elsevier
… Therefore, three coal-to-methyl glycolate (CtMG) processes with various … the dimethyl oxalate
to methyl glycolate process with Ag-based catalyst has the highest yield of methyl glycolate

Synthesis of methyl glycolate from the hydrogenation of dimethyl oxalate on Ag/SiO2 catalyst: the effects of Ag contents and promoters

S Cheng, D Mao, X Guo, J Yu - Reaction Kinetics, Mechanisms and …, 2019 - Springer
… The effect of Ag contents on the catalytic performance of the catalysts in the selective
hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG) was investigated. The result …

Optimization and prediction of catalysts for precise synthesis of methyl glycolate from dimethyl oxalate using machine learning coupled with particle swarm …

Q Yang, J Zhou, R Bao, D Rong, L Zhao… - Chemical Engineering …, 2024 - Elsevier
… for precise synthesis of methyl glycolate (MG) from dimethyl oxalate, this study proposed a
… Then the catalytic performance of the dimethyl oxalate to methyl glycolate (DtMG) process is …

Synthesis of methyl glycolate by hydrogenation of dimethyl oxalate over Cu-Ag/SiO2 catalyst

B Wang, Q Xu, H Song, G Xu - Journal of natural gas chemistry, 2007 - Elsevier
Methyl glycolate is a good solvent and can be used as feedstock for the … of dimethyl oxalate
(DMO) to MG is more economical and ecofriendly compared with its synthesis from methyl

Reaction temperature controlled selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over copper-hydroxyapatite catalysts

C Wen, Y Cui, X Chen, B Zong, WL Dai - Applied Catalysis B …, 2015 - Elsevier
… and carefully studied on the selective hydrogenation of dimethyl oxalate (DMO). The Cu/HAP …
relatively high and stable catalytic performance with methyl glycolate (MG) as the main …

Understanding size-dependent hydrogenation of dimethyl oxalate to methyl glycolate over Ag catalysts

G Dong, Z Luo, Y Cao, S Zheng, J Zhou, W Li, X Zhou - Journal of Catalysis, 2021 - Elsevier
… Ag catalysts are promising for the selective hydrogenation of dimethyl oxalate (DMO) to
methyl glycolate (MG), where the size of Ag nanoparticles strongly dominates their catalytic …

Toward rational catalyst design for partial hydrogenation of dimethyl oxalate to methyl glycolate: a descriptor-based microkinetic analysis

WQ Yan, JB Zhang, L Xiao, YA Zhu, YQ Cao… - Catalysis Science & …, 2019 - pubs.rsc.org
… examined the kinetics of diethyl oxalate hydrogenolysis to EG over copper catalysts and …
adsorption of diethyl oxalate, leading to the formation of ethanol and ethyl glycolate. The …

Enhanced chemoselective hydrogenation of dimethyl oxalate to methyl glycolate over bimetallic Ag–Ni/SBA-15 catalysts

J Zhou, X Duan, L Ye, J Zheng, MMJ Li… - Applied Catalysis A …, 2015 - Elsevier
dimethyl oxalate (DMO) to methyl glycolate (MG). The structure and physicochemical properties
of the catalysts were characterized using N 2 adsorption–desorption, X-ray fluorescence …

Selective Hydrogenation of Dimethyl Oxalate to Methyl Glycolate over Boron-Modified Ag/SiO2 Catalysts

S Cheng, T Meng, D Mao, X Guo, J Yu - ACS omega, 2022 - ACS Publications
… The addition of boron (B) as a promoter to the Ag/SiO 2 catalyst for the selective hydrogenation
of dimethyl oxalate (DMO) to methyl glycolate (MG) was investigated. A comparison of the …

Density-functional theory study on hydrogenation of dimethyl oxalate to methyl glycolate over copper catalyst: Effect of copper valence state

J An, X Wang, J Zhao, S Jiang, Y Quan, Y Pei, M Wu… - Molecular …, 2020 - Elsevier
… The development of high-performance copper (Cu)-based catalysts is critical to achieve the
industrial hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG). To understand …