Probing the structure sensitivity of dimethyl oxalate partial hydrogenation over Ag nanoparticles: A combined experimental and microkinetic study

RJ Zhou, WQ Yan, YQ Cao, JH Zhou, ZJ Sui… - Chemical Engineering …, 2022 - Elsevier
… in dimethyl oxalate (DMO) partial hydrogenation to methyl … The hydrogenation of DMO on
the two surfaces occurs along … step for the partial and deep hydrogenation of DMO is DMO …

Effect of Ti on Ag catalyst supported on spherical fibrous silica for partial hydrogenation of dimethyl oxalate

M Ouyang, J Wang, B Peng, Y Zhao, S Wang… - Applied Surface …, 2019 - Elsevier
… coverage of both hydrogen and dimethyl oxalate (DMO) on catalyst surface, which is
essential in promoting the performance of the catalyst in the hydrogenation of DMO. By using the …

Partial hydrogenation of dimethyl oxalate on Cu/SiO2 catalyst modified by sodium silicate

H Huang, B Wang, Y Wang, Y Zhao, S Wang, X Ma - Catalysis Today, 2020 - Elsevier
… applied in the partial hydrogenation of dimethyl oxalate (DMO) … % Na 2 SiO 3 in the partial
hydrogenation of DMO. The loss of … Thus, the further hydrogenation of MG can be prevented. …

Toward rational catalyst design for partial hydrogenation of dimethyl oxalate to methyl glycolate: a descriptor-based microkinetic analysis

WQ Yan, JB Zhang, L Xiao, YA Zhu, YQ Cao… - Catalysis Science & …, 2019 - pubs.rsc.org
Partial hydrogenation of dimethyl oxalate (DMO) has … the reaction mechanism for DMO
hydrogenation to MG on Cu, Ag, … , followed by the hydrogenation of methoxyl and the successive …

Perspectives on the active sites and catalyst design for the hydrogenation of dimethyl oxalate

RP Ye, L Lin, LC Wang, D Ding, Z Zhou, P Pan… - ACS …, 2020 - ACS Publications
… In summary, this review has provided insights into the active sites and key catalysts for
hydrogenation of dimethyl oxalate to high-value products. The new active sites, metal–support …

… of hydroxyapatite/graphite-supported bimetallic Cu–M (M= Cu, Fe, Co, Ni) catalysts for enhancing the partial hydrogenation of dimethyl oxalate to methyl glycolate

M Abbas, JM Wang, P Stelmachowski… - Catalysis Science & …, 2023 - pubs.rsc.org
hydrogenation reaction of dimethyl oxalate (DMO) that is derived from the green syngas (H 2
+ CO). Generally, the catalytic hydrogenation … MG through the partial hydrogenation of DMO …

… copper content and calcination temperature in the structural evolution and catalytic performance of Cu/P25 catalysts in the selective hydrogenation of dimethyl oxalate

B Wang, Y Cui, C Wen, X Chen, Y Dong… - Applied Catalysis A …, 2016 - Elsevier
… evaporation method for the selective hydrogenation of dimethyl oxalate (DMO) to ethylene
… copper dispersion, metal aggregation and thus poor hydrogenation activity. The 20Cu/P25-…

Tunable synthesis of ethanol or methyl acetate via dimethyl oxalate hydrogenation on confined iron catalysts

Y Sun, Q Ma, Q Ge, J Sun - ACS Catalysis, 2021 - ACS Publications
… and methyl acetate via dimethyl oxalate (DMO) hydrogenation. With the characteristic … for
DMO hydrogenation by now. The molecule-level mechanism of DMO hydrogenation is further …

Understanding size-dependent hydrogenation of dimethyl oxalate to methyl glycolate over Ag catalysts

G Dong, Z Luo, Y Cao, S Zheng, J Zhou, W Li, X Zhou - Journal of Catalysis, 2021 - Elsevier
… Ag catalysts are promising for the selective hydrogenation of dimethyl oxalate (DMO) to …
DMO hydrogenation to MG. A volcano-shape trend between the hydrogenation activity and the …

Kinetics Study of Hydrogenation of Dimethyl Oxalate over Cu/SiO2 Catalyst

S Li, Y Wang, J Zhang, S Wang, Y Xu… - Industrial & …, 2015 - ACS Publications
dimethyl oxalate (DMO) and the subsequent hydrogenation … 3 OH that is formed in the
hydrogenation step can be returned to … investigated with regard to the hydrogenation of DMO to …