… It is the aim of this paper to show some convincing examples of the indispensable role of
entropy in grain boundary segregation as a typical materials science phenomenon. …

… of entropy in the quantification of grain boundary segregation … Large differences are apparent
between the grain boundary … -entropy compensation effect cannot be considered if entropy …

… excess entropies of segregation (electronic, magnetic, nuclear) and focus on vibrational
entropy … It should be noted that the per-site segregation entropy defined in this work follows the …

… polycrystalline grain boundary segregation vibrational entropy … These entropy spectra are
very dependent on the fitting of … correlation between segregation energy and excess entropy as …

… enthalpy–entropy compensation … entropy of grain boundary segregation and the volume
bulk solid solubility. In addition, a fundamental relationship is derived between the segregation …

… Grain boundary (GB) segregation was experimentally studied in a bulk high entropy Cantor
… the weak segregation of Mn, implying co-segregation of Cr and Mn to the GBs. The strong …

… It is shown that entropy-driven grain boundary segregation would be a further … entropy-dominated
grain boundary segregation as it represents solute segregation at “anti-segregation” …

… We also show that the entropy of grain boundary segregation is a very important quantity …
individual issues listed above. Stabilization of grain boundaries by grain boundary segregation …

… Citation 68 The corresponding values of the standard enthalpy and entropy of grain
boundary segregation of antimony are Δ H Sb 0 = −23 kJ/mol and Δ S Sb 0 = +37 J/(mol.K).Citation …

… and intergranular regions into a modified solution model, and combined with entropic
contributions to establish the free energy of mixing. A series of equilibrium equations are finally …