Garnet electrolyte with an ultralow interfacial resistance for Li-metal batteries

Y Li, X Chen, A Dolocan, Z Cui, S Xin… - Journal of the …, 2018 - ACS Publications
… the lithium metal and garnet electrolyte. The solid line in Figure 4a represents the fitting
results with the equivalent circuit consisting of (R g )(R inter C inter )(W burg-short ). The carbon-…

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

K Fu, Y Gong, B Liu, Y Zhu, S Xu, Y Yao, W Luo… - Science …, 2017 - science.org
… the garnet solid electrolyte and the Li metal interface by … Li-metal alloy, which changes the
wettability of the garnet surface (… garnet/Li and 75 ohm·cm 2 for the surface-engineered garnet/…

Garnet solid electrolyte protected Li-metal batteries

B Liu, Y Gong, K Fu, X Han, Y Yao… - … applied materials & …, 2017 - ACS Publications
garnet/Li interface. Our results show that the symmetric cells with gel/garnet/gel hybrid electrolyte
and Li metal … the garnet SSE and metallic Li anode. Because minimal amounts of liquid …

Tuning the anode–electrolyte interface chemistry for garnet‐based solid‐state Li metal batteries

T Deng, X Ji, Y Zhao, L Cao, S Li, S Hwang… - Advanced …, 2020 - Wiley Online Library
… , but also form a stable Li‐ion conductive but electron‐insulating LPO‐derived solid‐electrolyte
interphase between the Li metal and the GSE. Consequently, the growth of Li dendrites is …

Negating interfacial impedance in garnet-based solid-state Li metal batteries

X Han, Y Gong, K Fu, X He, GT Hitz, J Dai, A Pearse… - Nature materials, 2017 - nature.com
… allows effective lithium ion transport between the lithium metal anode and garnet electrolyte.
We also demonstrate a working cell with a lithium metal anode, garnet electrolyte and a high…

Li3N-Modified Garnet Electrolyte for All-Solid-State Lithium Metal Batteries Operated at 40 °C

H Xu, Y Li, A Zhou, N Wu, S Xin, Z Li… - Nano …, 2018 - ACS Publications
… (16) Coating the garnet surface with a thin layer of ZnO has … of the garnet electrolyte by a
metallic lithium anode, and we speculate that the Zn reacts with the Li 2 CO 3 layer to create Li + …

Intrinsic lithiophilicity of Ligarnet electrolytes enabling high‐rate lithium cycling

H Zheng, S Wu, R Tian, Z Xu, H Zhu… - Advanced Functional …, 2020 - Wiley Online Library
… on lithium metal together with the garnet surface determines the Li/garnet interfacial
property. By removing the superficial impurity layer on the Li metal, Li/garnet electrolytes exhibit …

Investigating the dendritic growth during full cell cycling of garnet electrolyte in direct contact with Li metal

F Aguesse, W Manalastas, L Buannic… - … applied materials & …, 2017 - ACS Publications
… formation of lithium metal inside the garnet electrolyte during cycling. Part of the Li metal was
… However, dendritic lithium, also detected by solid-state NMR, was not observed by SEM. …

Transient behavior of the metal interface in lithium metalgarnet batteries

K Fu, Y Gong, Z Fu, H Xie, Y Yao, B Liu… - Angewandte Chemie …, 2017 - Wiley Online Library
… react with molten Li to form Li–Mg alloy, which brings the garnet electrolyte in close … Li. In
Figure S2, it shows a big gap at the interface between Li metal and pristine garnet electrolyte. …

Garnet solid electrolyte for advanced all‐solid‐state Li batteries

…, J Li, W Deng, H Shuai, S Li, Z Xu, J Li… - Advanced Energy …, 2021 - Wiley Online Library
… All the results suggested that Li 2 CO 3 layer was not intrinsic to the LLZO electrolyte, and it
… This work highlighted that the surface between the garnet electrolyte and Li metal needed to …