Doping by design: enhanced thermoelectric performance of GeSe alloys through metavalent bonding

Y Yu, C Zhou, T Ghosh, CF Schön, Y Zhou… - Advanced …, 2023 - Wiley Online Library
Doping is usually the first step to tailor thermoelectrics. It enables precise control of the
charge‐carrier concentration and concomitant transport properties. Doping should also turn …

Strong Phonon–Phonon Interactions Securing Extraordinary Thermoelectric Ge1–xSbxTe with Zn-Alloying-Induced Band Alignment

M Hong, Y Wang, T Feng, Q Sun, S Xu… - Journal of the …, 2018 - ACS Publications
The ability of substitution atoms to decrease thermal conductivity is usually ascribed to the
enhanced phonon-impurity scattering by assuming the original phonon dispersion relations …

Enhancing near-room-temperature GeTe thermoelectrics through In/Pb Co-doping

J Li, Q Hu, S He, X Tan, Q Deng, Y Zhong… - … Applied Materials & …, 2021 - ACS Publications
The traditional thermoelectric material GeTe has drawn much attention recently because of
the reported high thermoelectric performance of the rhombohedral phase in low-temperature …

Modulating structures to decouple thermoelectric transport leads to high performance in polycrystalline SnSe

Y Wang, S Bai, H Shi, Q Cao, B Qin… - Journal of Materials …, 2024 - pubs.rsc.org
In recent years, the thermoelectric properties of SnSe crystals have been rather impressive,
while those of polycrystalline SnSe are not ideal due to the grain boundary scattering, which …

Low Thermal Conductivity and High Thermoelectric Performance in (GeTe)1–2x(GeSe)x(GeS)x: Competition between Solid Solution and Phase Separation

M Samanta, K Biswas - Journal of the American Chemical Society, 2017 - ACS Publications
GeTe and its derivatives constituting Pb-free elements have been well known as potential
thermoelectric materials for the last five decades, which offer paramount technological …

High power factor and enhanced thermoelectric performance in Sc and Bi codoped GeTe: Insights into the hidden role of rhombohedral distortion degree

Z Liu, W Gao, W Zhang, N Sato… - Advanced Energy …, 2020 - Wiley Online Library
Modification of crystal symmetry induced by chemical doping or alloying is well known to
optimize the charge carrier transport properties in thermoelectric materials. Historically, the …

Contrasting roles of trivalent dopants M (M= In, Sb, Bi) in enhancing the thermoelectric performance of Ge0. 94M0. 06Te

Y Jin, D Wang, Y Zhu, L Su, T Hong, Z Wang, ZH Ge… - Acta Materialia, 2023 - Elsevier
Thermoelectric materials can achieve the interconversion of electricity and heat, providing
potential for power generation. It is a challenge to elevate conversion efficiency due to the …

High-performance GeTe thermoelectrics in both rhombohedral and cubic phases

J Li, X Zhang, X Wang, Z Bu, L Zheng… - Journal of the …, 2018 - ACS Publications
GeTe experiences phase transition between cubic and rhombohedral through distortion
along the [111] direction. Cubic GeTe shares the similarity of a two-valence-band structure …

Metavalent bonding in GeSe leads to high thermoelectric performance

D Sarkar, S Roychowdhury, R Arora… - Angewandte Chemie …, 2021 - Wiley Online Library
Orthorhombic GeSe is a promising thermoelectric material. However, large band gap and
strong covalent bonding result in a low thermoelectric figure of merit, zT≈ 0.2. Here, we …

Band and phonon engineering for thermoelectric enhancements of rhombohedral GeTe

H Liu, X Zhang, J Li, Z Bu, X Meng… - ACS applied materials …, 2019 - ACS Publications
Rhombohedral GeTe can be approximated as the directional distortion of the cubic GeTe
along [111]. Such a symmetry-breaking of the crystal structure results in an opposite …