Residual water in ionic liquids: clustered or dissociated?

JESJ Reid, AJ Walker, S Shimizu - Physical Chemistry Chemical …, 2015 - pubs.rsc.org
How do residual water molecules in ionic liquids (ILs) interact with themselves, as well as
with the ions? This question is crucial in understanding why the physical properties of ILs …

What determines the miscibility of ionic liquids with water? Identification of the underlying factors to enable a straightforward prediction

M Klähn, C Stüber, A Seduraman… - The Journal of Physical …, 2010 - ACS Publications
Whether an ionic liquid (IL) is water-miscible or immiscible depends on the particular ions
that constitute it. We propose an explanation, based on molecular simulations, how ions …

Influence of the Water Content on the Structure and Physicochemical Properties of an Ionic Liquid and Its Li+ Mixture

VL Martins, BG Nicolau, SM Urahata… - The Journal of …, 2013 - ACS Publications
The effect of water on the hydrophobic ionic liquid (IL) 1-n-butyl-2, 3-dimethylimidazolium bis
(trifluoromethanesulfonylimide) and its Li+ mixture was evaluated. The electrochemical …

Ionic liquid/water mixtures: from hostility to conciliation

Y Kohno, H Ohno - Chemical Communications, 2012 - pubs.rsc.org
Water was originally inimical to ionic liquids (ILs) especially in the analysis of their detailed
properties. Various data on the properties of ILs indicate that there are two ways to design …

The properties of residual water molecules in ionic liquids: a comparison between direct and inverse Kirkwood–Buff approaches

T Kobayashi, JESJ Reid, S Shimizu, M Fyta… - Physical Chemistry …, 2017 - pubs.rsc.org
We study the properties of residual water molecules at different mole fractions in
dialkylimidazolium based ionic liquids (ILs), namely 1-ethyl-3-methylimidazolium …

Interactions in water–ionic liquid mixtures: comparing protic and aprotic systems

JESJ Reid, RJ Gammons, JM Slattery… - The Journal of …, 2017 - ACS Publications
The sensitivity of ionic liquids (ILs) to water affects their physical and chemical properties,
even at relatively low concentrations, yet the structural thermodynamics of protic IL–(PIL−) …

Confirmation of local water structure confined in ionic liquids using H/D exchange

Y Yoshimura, T Mori, K Kaneko, K Nogami… - Journal of Molecular …, 2019 - Elsevier
We investigated the local structure of water molecules confined inside ionic liquid (IL)
nanodomain structures of 1-butyl-3-methylimidazolium tetrafluoroborate,(abbreviated as …

Effect of water on the structure of a prototype ionic liquid

O Borodin, DL Price, B Aoun, MA González… - Physical Chemistry …, 2016 - pubs.rsc.org
The influence of water on the structure of a prototype ionic liquid (IL) 1-octyl-3-
methylimidazolium tetrafluoroborate (C8mimBF4) is examined in the IL-rich regime using …

How water manifests the structural regimes in ionic liquids

AP Singh, RL Gardas, S Senapati - Soft matter, 2017 - pubs.rsc.org
Ionic liquids (ILs) are being considered as greener alternatives to the conventional organic
solvents. However, highly viscous nature of ILs often limits their applications. Hence studies …

Towards an understanding of the mutual solubilities of water and hydrophobic ionic liquids in the presence of salts: the anion effect

LIN Tomé, FR Varanda, MG Freire… - The Journal of …, 2009 - ACS Publications
The understanding of the specific interactions between salt ions and ionic liquids (ILs) in
aqueous solutions is relevant in multiple applications. The influence of a series of anions on …