Phase Modulation Enabled High Thermoelectric Performance in Polycrystalline GeSe0.75Te0.25

Z Wang, H Wu, B Zhang, L Dai, Y Huo… - Advanced Functional …, 2022 - Wiley Online Library
The structure–property link is inherent to materials. Hexagonal Ge4Se3Te phase, with
special Ge–Ge cationic bonding and distinctive from other IV–VI compounds, reveals …

Structure-Dependent Thermoelectric Properties of GeSe1–xTex (0 ≤ x ≤ 0.5)

Z Wang, H Wu, M Xi, H Zhu, L Dai… - … Applied Materials & …, 2020 - ACS Publications
GeSe was theoretically predicted to have thermoelectric (TE) performance as high as SnSe.
However, the relatively high TE performance was not achieved experimentally in doped …

Achieving Superior Thermoelectric Performance in Ge4Se3Te via Symmetry Manipulation with I–V–VI2 Alloying

M Guo, HH Cui, W Guo, Z Chen, H Ming… - Advanced Functional …, 2024 - Wiley Online Library
Although orthorhombic GeSe is predicted to have an ultrahigh figure of merit, ZT≈ 2.5, up to
now, the highest experimental value is≈ 0.2 due to the low carrier concentration (nH≈ 1018 …

Synergetic optimization of electronic and thermal transport for high-performance thermoelectric GeSe–AgSbTe 2 alloy

M Yan, X Tan, Z Huang, G Liu, P Jiang… - Journal of Materials …, 2018 - pubs.rsc.org
Rhombohedral GeSe is a promising p-type thermoelectric material with a multivalley band
structure. However, its figure of merit ZT, especially average ZT is still relatively low …

Crystal symmetry enables high thermoelectric performance of rhombohedral GeSe (MnCdTe2) x

X Li, Z Liang, J Li, F Cheng, J He, C Zhang, J Li, F Liu… - Nano Energy, 2022 - Elsevier
High symmetry favors high power factor by virtue of the balanced Seebeck coefficient and
carrier mobility, nonetheless, the role of crystal symmetry in enhancing the material's …

Anionic regulation and valence band convergence boosting the thermoelectric performance of Se-alloyed GeSb2Te4 single crystal

P Chen, B Zhang, Z Zhou, S Zheng, D Zhang, Y Yan… - Acta Materialia, 2023 - Elsevier
Abstract GeSb 2 Te 4, a layer-structured pseudo-binary chalcogenide, is a promising
thermoelectric material with low lattice thermal conductivity ensured by the van de Waals …

Enhanced thermoelectric performance of band structure engineered GeSe 1− x Te x alloys

D Sidharth, ASA Nedunchezhian, R Akilan… - Sustainable Energy & …, 2021 - pubs.rsc.org
Nanostructured thermoelectric materials of GeSe1− xTex (0≤ x≤ 0.2) alloys were prepared
by mechanical ball milling, followed by consolidation under a hydrogen atmosphere and …

[PDF][PDF] Two-step phase manipulation by tailoring chemical bonds results in high-performance GeSe thermoelectrics

W Yao, Y Zhang, T Lyu, W Huang, N Huang, X Li… - The Innovation, 2023 - cell.com
In thermoelectrics, phase engineering serves a crucial function in determining the power
factor by affecting the band degeneracy. However, for low-symmetry compounds, the …

High Thermoelectric Performance and Enhanced Mechanical Stability of p-type Ge1–xSbxTe

S Perumal, S Roychowdhury, DS Negi… - Chemistry of …, 2015 - ACS Publications
High thermoelectric figure of merit, zT, of∼ 1.85 at 725 K along with significant cyclable
temperature stability was achieved in Pb-free p-type Ge1–x Sb x Te samples through …

Synergistically Optimized Thermal Conductivity and Carrier Concentration in GeTe by Bi–Se Codoping

L Xu, G Wu, R Wang, Z Yan, J Cai, J Yang… - … Applied Materials & …, 2022 - ACS Publications
The GeTe compound has been revealed to be an outstanding thermoelectric compound,
while its inherent high thermal conductivity restricts further improvement in its performance …