Visible-light-induced 1, 6-enyne-triggered C–Br bond homolysis of bromomalonates has
been developed. This transition-metal-free, photocatalyst-free, and oxidant-and additive-free …

Radical annulative carbohalofunctionalization of 1, n-enynes via atom transfer processes
constitutes an efficient and practical synthetical strategy for accessing halogenated cyclic …

A manganese-and borane-mediated synthesis of isobenzofuranones from esters and
oxiranes is developed. The reaction proceeded at aromatic, heteroaromatic, and olefinic C …

The selective halogenation of the inert C–C bonds of alcohol-based feedstock is of
tremendous significance in synthetic chemistry. Previous halogenation usually requires a …

A visible-light-induced photoredox-catalyzed bromoetherification of alkenols is described.
This approach, with CBr 4 as the bromine source through generation of bromine in situ …

A hydroxyl‐assisted, organophotoredox/cobalt dual catalyzed annulation of 2‐
propynolphenols to form 2‐hydroxymethyl‐benzo [b] furans was developed by employing 1 …

The first example of using commercially available and cheap nBu4NBr as a cocatalyst,
which is photoactivated by 4-CzIPN, to selectively activate the α-C–H bond of …

In the last decades, many C− C bond‐forming reactions have been developed, whereas less
attention has been paid to the design of strategies involving C− C bond cleavage. We report …

C–O σ-bonds in multifaceted benzoin derivatives can be effectively cleaved as acetates
using catalytic amounts of [Ru (bpy) 3] Cl2 as photoredox catalyst in combination with …

Bromine induced spiro cyclization of biaryl ynones facilitated the synthesis of spiro [5, 5]
trienones suitable for extended functionality at the C (3′) position. Herein, a step-economic …